First of all, this is two people. Gibbs is famous for publishing three epoch-making papers from 1877 to 1878. Mainly these three articles put forward the concepts of Gibbs free energy function and chemical potential, put forward the comparison of multiphase equilibrium, and systematically summarized classical thermodynamics. Especially, the balance problem of thermal system is completely solved theoretically. Belongs to the person who lays the theoretical foundation for thermodynamics.
About Dion, another legend. Although there are two Gibbs-Duheim equations and Duheim-Majoor equations that often study solution thermodynamics, they are introduced more often.
Talk too much. Find it yourself. Gibbs, Baidu Encyclopedia. Dion can look at this web page. /index.php? Document-View-135502