The School of Chemical Engineering and Materials Science of Jiang University of Technology has seven disciplines, including chemical engineering, applied chemistry, industrial catalysis, chemical technology, materials science, pesticide science and chemistry, among which industrial catalysis is the national key discipline (cultivation), applied chemistry, industrial catalysis, new materials and processing engineering are the key disciplines of in-service graduate students in Zhejiang Province, and chemical engineering and materials science are the key disciplines in Zhejiang Province.
Recently, Jia Yixia's research group of School of Chemical Engineering, Zhejiang University of Technology has made important progress in the study of asymmetric Friedel-Crafts reaction. In the top international journal angew.chem.int.ed., based on "Double analysis of redox announcements of nitroalkynes and indoles: realizing the selective construction of indoline -3- one with a four-dimensional century". Rs ",the asymmetric Friedel-Crafts alkylation with nitrone as alkylation reagent was reported for the first time. Using gold trichloride/chiral phosphoric acid composite catalyst, the cyclization/alkylation reaction of o-nitrophenylaceyne and indole was efficiently connected in series, and indole ketone compounds with 2- position quaternary carbon chiral center were constructed with high selectivity, which provided a fast and effective method for synthesizing important natural products and bioactive molecules containing such structures.
The research was mainly completed by Mr. Liu and Master Ye Shichun of Zhejiang University of Technology, and Chen Jingbiao, a sophomore, participated in the optimal catalyst. Synthesis of pentafluorophenyl chiral phosphoric acid. This work is the second important research achievement reported by the research group in the field of asymmetric Friedel-Crafts reaction after J. Am. Chemistry. SOC.20 13， 135，2983。 This research is strongly supported by the National Natural Science Foundation, the New Century Outstanding Talents Support Program of the Ministry of Education and the Zhejiang Outstanding Youth Fund.
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