Porous organometallic complexes were synthesized by reasonable molecular design, and chiral catalysts supported by paramagnetic nanoparticles were used in various asymmetric catalysis and synthesis. A large class of 4,4'-substituted BINAP ligands were synthesized and applied to asymmetric synthesis catalyzed by transition metals such as ruthenium (Ru) and rhodium (Rh). A functional polymer based on Gd-DOTA was synthesized and applied to highly sensitive magnetic resonance imaging agent (MRI-CA). Twenty-six papers were published, and 26 papers were included in SCI and cited more than 500 times. There is also an American patent and a European patent.