It is difficult to understand Freud's works without the basis of psychoanalysis. It is suggested to start with the introduction of books, and then read Freud's Introduction to Psychoanalysis, which is equivalent to Freud's own Introduction to Psychoanalysis.
There are also Psychology of Love, Interpretation of Dreams, Research on Hysteria, Pathology of Daily Life, Three Treatises on Sexology, Outline of Psychoanalysis, Self and Collective Psychoanalysis, Civilization and Dissatisfaction, Da Vinci and a Childhood Memory, and so on.