Special topics in college chemistry
The standard molar enthalpy of formation (L) of 16.H2O only needs to be generated 16. H2O (L of water, so you need to divide the reaction enthalpy by 2 to get -286kJ/mol (sign, no need to change, because the enthalpy of formation is also enthalpy change) 17. First, the concentration of CD (dilute solution of acid, diluted H+) can be excluded. Then dilute it to the original 1/4. Because HCN is a weak acid, the concentration of H+ will not decrease so much. You can choose A from the perspective of multiple-choice questions. More strictly speaking, for the dilute solution of monobasic weak acid, c(H+)= radical sign (Ka×c) can be obtained from the ionization equilibrium equation, where c is the concentration of acid solute. (In the derivation of this formula, it is considered that the concentrations of H+ and acid radical ions are approximately equal. Therefore, when c is 1/4, c(H+) is 1/2.