Current location - Education and Training Encyclopedia - University rankings - College physical thermodynamics
College physical thermodynamics
First question, positive solution on the first floor.

The second question is that the first floor is wrong. Now the entropy change is calculated as follows:

1, and find the equilibrium temperature t after mixing.

Taking two liquids as a system, assuming that cp is constant, the expansion coefficient of the liquid has nothing to do with temperature, so there are

Q=0 and W=0.

So Mcp(T-T 1)+Mcp(T-T2)=0.

T=(T 1+T2)/2 is obtained.

2. Entropy change of liquid

According to the definition and meaning of the question, there is ds = Δ q/t = CP × dt/t.

So for the liquid with T 1, its entropy becomes ds1= m× CP× dt/t.

Its temperature ranges from T 1→(T 1+T2)/2, so the above integral is: △ s1= mcpln [(t1+t2)].

Similarly, △ S2 = mcpln [(t1+t2)/(2t2)]

Therefore, after mixing, the total entropy of the system becomes

△s=△s 1+△s2=m×cp×ln[(t 1+t2)^2/(4t 1×t2)]

Over.