W =-δ n (gas) RT
δU = Q+W
δS =δH/T
δA =δU-tδS,
δG =δH-tδS .
(2) Initial state: 373K, 130kPa liquid water; Final state: 373K, 130kPa steam.
From the initial state to 373K, 100kPa liquid water, Gibbs free energy becomes δ G (1).
From 373K, 100kPa liquid water to 373K, 100kPa water vapor, Gibbs free energy changes to δ g (2) = 0 (reversible phase transition).
From 373K, 100kPa water vapor to the final state: 373K, 130kPa water vapor, Gibbs free energy becomes δ G (3).
δG =δG( 1)+δG(2)+δG(3)
= v δ p+0+nrtln (130/100) v = molar mass divided by density, in cubic meters.