During his teaching career, he has successively produced 16 academicians among his students. The list is as follows: China, academician of China Academy of Sciences in Chen Jiayong, 1943 graduated from the Department of Chemistry of National Central University (now Nanjing University of Technology). Academician Liang, Chinese Academy of Sciences, 1942 was admitted to the Department of Chemical Engineering of Central University (now Nanjing University of Technology). Min Enze, academician of China Academy of Sciences, academician of China Academy of Engineering, expert in petrochemical catalysts, 1946 graduated from the Department of Chemical Engineering of National Central University (now Nanjing University of Technology). Min Enze and Lu Wanzhen (female) are classmates. Lu Wanzhen, an analyst and petrochemical expert of China Academy of Sciences, and Hu China, an expert in organic synthetic chemistry of Academy of Sciences 1946 graduated from the former Department of Chemistry of Central University (now Nanjing Institute of Technology), and Zhang Cunhao 1947, a physical chemist of China Academy of Sciences, graduated from the Department of Chemical Engineering of Nanjing Central University (now Nanjing Institute of Technology), molecular reaction dynamics Jia and Zhu Qihe, academicians of China Academy of Sciences 1 In 947, he graduated from the Department of Chemical Engineering of Nanjing Central University (now Nanjing University of Technology), Lu Zhongwu, academician of China Institute of Technology, thermal energy engineering expert 1950, academician of China Institute of Technology, petrochemical machinery expert 1952, and Chen Yi, academician of China Academy of Sciences, graduated from Nanjing University (now Nanjing University of Technology, mechanical nonmetallic material expert 1 In 956, he graduated from the Department of Chemical Engineering of Nanjing Institute of Technology (now Southeast University), petrochemical expert 1967 from Nanjing Institute of Chemical Technology (now Nanjing University of Technology), material science of Jiang China Institute of Technology 1960 from Nanjing Institute of Chemical Technology (now Nanjing University of Technology), and inorganic nonmetallic material expert 65438 from China Institute of Technology. +0983 Nanjing University of Chemical Technology (now Nanjing University of Technology) graduated from Ouyang Pingkai China Institute of Engineering 198 1 and came to work in Nanjing Institute of Chemical Technology (predecessor of Nanjing University of Technology). Xu Nanping China Institute of Engineering graduated from Nanjing Institute of Chemical Technology with a doctorate in chemical engineering 1989. According to the National Library Reference Alliance, two masters are trained every hour. 52 doctors, the details are as follows: the title of the annual paper was awarded by the author's degree. In 2005, Cui Mifen, Ph.D., Nanjing University of Technology, 2007, Ouyang Jia, Ph.D., 2003, Gu Heping, Ph.D., Nanjing University of Technology, 2002, Solution. Dr Guan Guofeng's 2002 study on adsorption refrigeration working pair and its refrigeration process; Dr. Cui Qun 2004 Study on Nickel Catalyst for Separation and Production of P-aminophenol by Ceramic Membrane; Research and application of Dr. Jinshan 2004 integrated ceramic membrane emulsifier: Dr. Jing Wenheng faced Chinese medicine in 2004. Design and application of ceramic membrane in liquid extraction system Li, Ph.D., Nanjing Institute of Technology, 2004, numerical simulation of material flow in silo, Xiao, Ph.D., 2003, application of integrated modeling method and advanced control technology in two chemical processes, Dr., Nanjing Institute of Technology, 2003, expert system for spectrophotometric analysis, Chen, Ph.D., Nanjing Institute of Technology, 2003, preparation and research of perovskite oxygen permeable materials, Dr. Yang Li 2002 Design and application of ceramic membrane materials for titanium dioxide industrial wastewater treatment Dr. Zhao Yijiang 2002 Preparation and characterization of ethylene/ethane complex separation adsorbent Dr. Mei Hua 2002 Research on complete sets of ceramic membrane equipment and engineering application technology Dr. Xing 2002 Research on nanofiltration concentration and desalination mass transfer process Dr. Yang Gang 2002 Research on ceramic membrane bioreactor Dr. Xu Nong Nanjing Institute of Technology 2002 Study on methane catalytic oxidation in mixed conductor compact oxygen permeable membrane reactor. Dr. Wei Ping, Ph.D., Nanjing University of Technology, 2002 Study on the Preparation of D-D-Amino Acids, Dr. Kelvin Cui, Ph.D., Nanjing University of Technology, 200 1 NAA Zeolite Molecular Sieve Membrane Synthesis and Permeability Research, Dr. Dong Qiang, Preparation of 2000 Zirconia Ceramic Ultrafiltration Membrane and Related Basic Technology Research. Study on Enhanced Transfer Heterogeneous Catalytic Internal Circulation Airlift Reactor Preparation of High-quality and Low-cost Potassium Titanate Whiskers by Dr. Nanjing University of Chemical Technology 2000 and Its Application in Composite Materials Feng Xin Dr. Nanjing University of Chemical Technology 1999 Study on Simulation of Potassium Sulfate Production Process and Its Dissolution Kinetics Chen Master of Nanjing University of Chemical Technology 1999 Mixed Conductive Compact Oxygen Permeable Ceramic Membrane Nanjing University of Chemical Technology. Doctor 1999 "Study on TiO _ 2 microfiltration membrane and ultra-thin Pd/TiO _ 2 composite membrane" Dr. Wu Liqun 1999, Dr. 200 1, Synthesis of monodisperse titanium dioxide nanoparticles and its application in hydrogen production by photolysis of water, Master of Nanjing University of Technology1999. Experimental Research and Mathematical Simulation of Photocatalytic Ceramic Membrane Reactor Dr. Shi, Ph.D. 1999 Study on Adsorption Equilibrium and Kinetics of Mixed Solution, Dr. Nanjing University of Chemical Technology 1999 Study on Chemistry and Phase Equilibrium of Electrolyte Solution for Process Simulation, Dr. Ji Xiaoyan, Dr. Nanjing University of Chemical Technology 1999 Study on Preparation of Supported Perovskite Oxygen Permeable Membrane and Synthesis of Gas-tube Compact Membrane Reactor by Partial Oxidation of Methane, Ph.D. 654, Nanjing University of Chemical Technology. 38+0999 Study on the Treatment of Oily Emulsion Wastewater 1998, Master Wang, Nanjing University of Chemical Technology, Basic Research on the Application of Pulverized Coal Combustion, High-temperature Heat Transfer and Calcined Clinker Thermal Process Ye Xuchu 1998 Molecular Dynamics Simulation of Fluid Microstructure and Diffusion Characteristics, Ph.D. 1998 Basic Research and Application Development of Ceramic Microfiltration Membrane System Zhong Jing. Ph.D. 1998, Ph.D. 1997, Ph.D. 1997, Purification of Trace Carbon Monoxide in Nitrogen-containing Gas, Ph.D. 1997, Study on Gas-solid Adsorption Equilibrium and Adsorption Kinetics, Ma. 1997, Dr. Shen Shiquan, Dr. 1997, research and application of supercritical fluid deposition technology, Dr. Wang Chaohui, preparation and industrialization of alumina microfiltration membrane, Dr. Wang Pei, Dr. 1996. Characterization and applied research Dr. Huang Pei Nanjing University of Chemical Technology 1996 Dr. Yun Zhi Nanjing University of Chemical Technology 1995 Dr. Fan Yiqun of Nanjing University of Chemical Technology 1995 Dr. Dong Junhang of Nanjing Institute of Chemical Technology 1994. Research on Equilibrium Thermodynamics Zhang, Ph.D. 1992 Relativity of Statistical Thermodynamics and Its Application, Ph.D. 1992 Research on Phase Equilibrium in Critical Zone, Ph.D. 1989 Research on Phase Equilibrium of High Pressure Fluid, Ph.D. 198 Nanjing Institute of Chemical Technology. 8 Thermodynamic Study of Strong Electrolyte Mixed Solvent System Dr. Nanjing Institute of Chemical Technology 1988 Study on Thermodynamic Properties of Excess Non-electrolyte Solution Dr. Shen of Nanjing Institute of Chemical Technology studied rigorously and meticulously. When he was the executive deputy editor-in-chief of Encyclopedia of China Chemical Industry Volume, he devoted a lot of efforts to compiling this masterpiece. He not only shouldered heavy organizational leadership work, but also personally wrote and revised several important items, and some even revised the manuscript. He personally wrote several chapters in the Comprehensive Theory. He also wrote Mass Transfer and Absorption in the Handbook of Chemical Engineering, and presided over the translation of books such as Mass Transfer, Fluidization Engineering and Design and Calculation of Finned Tube Heat Exchanger.
Shi Jun attaches great importance to scientific research. As early as when I was studying in Tsinghua University, I published three papers (in English) on the laws and organic qualitative analysis of preparing color smoke screens in Journal of Tsinghua University and Journal of chinese chemical society. His master's thesis "The relationship between screening and properties of mechanical wood pulp" at the University of Maine was divided into two papers by his tutor and published in the American paper professional magazine. From 65438 to 0957, Yang Nanru's graduate thesis "The relationship between the granularity of high alumina cement raw meal and firing temperature" was published in the first issue of Journal of Silicate. In adversity, Shi Jun did the turbulence tower experiment in 1965. Since 1972, the research on membrane separation has achieved gratifying results, but due to the limitations of experimental conditions at that time, it was impossible to go further. Since 1974, Shi Jun has participated in the performance evaluation test of domestic fillers (mainly Lacey ring), and has published 4 papers (unsigned). The whole test process of several fillers, such as the determination of test scheme, the design and installation of devices, the determination of data, collation and comparison, the application of calculation formulas, and the writing of test reports, was carried out under his personal auspices. Some contents about the test method, such as the selection principle of the test system, data processing and expression methods, have been quoted by relevant domestic parties. 1979, Shi Jun led his assistant to start systematic research. The research content mainly includes three aspects: experimental determination of thermodynamic properties of fluid, and study of solution thermodynamics by chromatography and membrane separation technology. Shi Jun believes that engineering science is still an experimental science. The basic physical properties used in the research, design and development of chemical engineering need more accurate experimental measurement. Since the early 1980s, he has set out to establish a measurement center for basic thermodynamic properties in a planned way, studied a wide range of phase equilibria, volume properties and excess properties, trained a group of professionals engaged in this research, and published more than 30 papers in important journals at home and abroad. In the aspect of fluid phase equilibrium, it is expensive and time-consuming to measure the thermodynamic properties of fluid under high pressure, so the useful measured data are extremely scarce so far, which affects the theoretical progress in this field. In view of this, Shi Jun, Wang Yanru and others built a high-precision high-pressure phase equilibrium device, and extensively measured the phase equilibria of chlorofluorocarbon substitution system and high-pressure carbon dioxide gas field system, as well as the near-critical region of multicomponent system and the critical trajectory of mixture. After the relevant papers were published in important journals at home and abroad, experts and databases in more than 10 countries and regions sent letters asking for printed copies. Some measurement results corrected the deviation of previous measurement data and expanded the measurement range. Recently, based on the original static method and Bummit expansion method, a simple method for simultaneously measuring the phase equilibrium composition and equilibrium phase density of high-pressure fluid on one device has been successfully established, which provides a new means for quickly and effectively obtaining the basic physical properties of fluid under high pressure. In addition, together with his assistants, he set up an accurate Bummit method device for measuring fluid compressibility factor, which is used to obtain the basic P-V-T data of mixed gas under high pressure. When the paper was published in an important foreign journal, the reviewer of the American Center for Thermal Research (TRC) thought that the accuracy of the compression factor of the mixed gas measured in this paper "has reached the best level of similar devices". While establishing a high-pressure device, Shi Jun and his collaborators also made extensive and practical measurements and studies on the phase equilibria under atmospheric pressure, including vapor-liquid, liquid-liquid and liquid-solid phase equilibria. More than 65,438+00 papers published in this field provide essential basic physical data for developing and designing chemical processes, such as solvent extraction of C5 hydrocarbons, separation of ethylbenzene-methylstyrene, separation and purification of important solvent 4- methyl-pentanone, and solubility of methyl chloride in trimethylbenzene.
The mixing heat (excess enthalpy) of solution is a basic physical property with important theoretical significance and engineering design application. After years of efforts, Shi Jun and his collaborators improved and gradually perfected a set of devices for accurately measuring micro thermal effects. The device can be used to measure the trace thermal effect (which can sensitively reflect 1 joule) produced or absorbed by various pure substances or biological substances during mixing, reaction or other physical and chemical changes. In this field, the basic physical data such as mixing heat of various binary ternary systems of organic compounds, excess enthalpy, dilution heat and solution heat of strong electrolyte mixed solvent system have been measured successively, and nearly 10 papers have been published in the International Journal of Chemical Thermodynamics.
Electrolyte aqueous solution containing organic matter is a complex system often encountered in industrial practice. There are few data about phase equilibrium, and its thermodynamic characteristics are difficult to be predicted and calculated by general electrolyte solution theory or semi-empirical model. Shi Jun and his collaborators used the difference of conductivity of solutions with different concentrations combined with conductometric titration, and adopted the continuous determination method of ion-selective electrode to conveniently and accurately determine the phase equilibrium composition of various organic aqueous solutions of strong electrolytes, and the measurement accuracy was significantly improved. Related research was published in international academic conferences and was well received by many experts.
The key to establish the equation of state of fluid from the theory of statistical mechanics is that it is difficult to calculate the integral containing the product of radial distribution function and potential energy function. Scholars at home and abroad generally use numerical integration to deal with or simplify the radial distribution function g(r). Shi Jun and his collaborators treated this integral as a whole quantity, quoted the compressibility equation of statistical mechanics, and obtained the analytical calculation formula of this integral by simplifying the form of potential energy function, thus directly obtaining the state equation with simple form and high calculation accuracy, and applied this idea to the study of the local composition of fluid, connecting the microscopic quantity of local composition with the macroscopic quantity of compressibility for the first time, providing a new method for the study of local composition. The new local composition model has been successfully used to calculate the vapor-liquid equilibrium of strongly non-ideal systems.
Solution thermodynamics is an important part of chemical thermodynamics and the basis of chemical engineering. As a thermodynamic researcher, Shi Jun led the researchers to study the method of chromatographic determination of thermodynamic properties with only one gas chromatograph according to the latest research trends at home and abroad at that time and the conditions of the institute. After 10 years of efforts, Shi Jun and Wang Shaokun have trained many graduate students in this field and published more than 20 papers. In addition to measuring the infinite dilution activity coefficients of many systems by chromatography, they also improved the model and method of predicting the activity coefficients in the whole concentration range by using R and (dr/dx)x=0 proposed by foreign scholars in the mid-1970s, and established their own empirical correlation for predicting vapor-liquid equilibria, which achieved better prediction accuracy than the existing UNIFAC group contribution method in the world. They also measured the infinite dilution activity coefficient of volatile solute in mixed non-volatile solvents by chromatograph, studied the parametric multiple solutions of Wilcon equation, the prediction of vapor-liquid equilibrium of symmetric and multicomponent systems, and studied the step pulse method for measuring vapor-liquid equilibrium, so that chromatography can be extended to various systems containing polar components and polymer components for adsorption research and calculation of gas-solid equilibrium. The determination of adduct constant of the system with adduct formation was studied, and the solid-liquid equilibrium of the system was predicted. On the basis of determining the infinite dilution activity coefficient, the modified separation condensation energy density model for predicting the infinite dilution activity coefficient proposed by foreign countries in the 1980 s was improved, and the prediction accuracy was improved.
In the aspect of membrane separation, Shi Jun and his collaborators mainly engaged in the research of gas membrane separation, and also engaged in the research of pervaporation process and the performance of liquid membrane separation equipment. More than 30 papers (including international conference reports) have been published before and after. In the early 1980s, Shi Jun and Chen Mingde used the modified fluorine-containing resin membrane to permeate and separate the mixed gas of ammonia, hydrogen and nitrogen, providing a new method to separate ammonia from the mixed gas, which was a pioneering work at home and abroad. After the report of Tokyo International Conference on Membrane and Membrane Process 1986, it attracted the attention of all parties and has been cited by foreign scholars in related papers so far.
1985, Shi Jun, Zhuang Zhenwan, etc. The gas membrane separation was studied systematically. Single and double membrane permeators and continuous membrane towers are composed of various domestic membranes. Taking He-N2-CH4, CH4-CO2-N2 and other mixed gases as objects, separation experiments were carried out, and the mechanism of gas dissolution and permeation in the membrane was expounded theoretically. The gas separation calculation methods of various membrane permeators and their systems are also explored, and a new mathematical model is established. This new model is suitable for the separation calculation of mixed gas with arbitrary component fraction in different types of membrane permeators and their systems. In addition, they also established a general thermodynamic model of gas dissolution and permeation mechanism in the membrane, and a permeation mechanism model with plasticizing effect. At present, Shi Jun, Nan Yang and others are studying the national key topic inorganic membrane and membrane reactor.
In the aspect of liquid membrane separation, Shi Jun and Qiu mainly studied the hydrodynamic performance, droplet diameter distribution and mass transfer effect of the oil-emulsion-water system in the porous turntable tower, in order to explore the possibility of using the porous turntable tower for liquid membrane separation.
In recognition of Shi Jun's outstanding achievements, the Ministry of Chemical Industry awarded him the honorary title of "Excellent Expert with Significant Contribution to National Chemical Industry" and became the first batch of experts in China who enjoyed special government allowance. Shi Jun, member of the Sixth and Seventh CPPCC, academician of China Academy of Sciences, first-class professor of chemical engineering, honorary director of the Department of Chemical Engineering of Nanjing Institute of Chemical Technology. At the same time, he is also a member of the chemistry evaluation group of the National Natural Science Foundation of China, the head of the chemical industry group, the member of the sinopec group Technical and Economic Advisory Committee, the director of the academic Committee of the State Key Laboratory of Chemical Engineering, the member of the academic Committee of the State Key Laboratory of Coal Conversion, the executive director of the China Chemical Industry Society, the chairman of the Jiangsu Chemical Industry Society, the deputy director of the editorial board of the Encyclopedia of Chemical Engineering, the director of the editorial board of the Chemical Engineering Manual, the deputy editor of the Journal of Chemical Engineering and the China Journal of Chemical Engineering.
Over eighty years old, Shi Jun, full of energy and quick thinking, continues to train a group of young people to stand out. Some of them have won the Humboldt Research Scholarship and the Henry Fok Education Fund Award, and some have won the honorary title of "Excellent Young Scientists", and have generally made great achievements in their respective research fields. This shows that Shi Jun's career has successors.
1934 graduated from the chemistry department of Tsinghua University. 1936, obtained a master's degree in chemical engineering from the University of Maine. 1936 to 1938 studied in the graduate school of MIT. After returning to China, he served as a professor at Chongqing University and Central University, and head of the Department of Chemical Engineering. After the founding of People's Republic of China (PRC), he served as a professor at Nanjing University, Nanjing Institute of Technology and Nanjing Institute of Chemical Technology, director of the Department of Chemical Engineering, member of the Department of Chemistry of China Academy of Sciences, member of the first discipline evaluation group of the State Council Academic Degrees Committee, deputy editor-in-chief of the Chemical Volume of Encyclopedia of China, the fourth executive director of China Chemical Industry Society and the fifth chairman of Jiangsu Chemical Industry Society. Member of the Jiu San Society. He is a member of the Sixth Committee of China People's Political Consultative Conference. Specializing in chemical engineering. 1952, China silicate technology specialty was established. Handbook of gas absorption in chemical engineering and chemistry of cement and concrete. 1 Shenzhen. Permeability of ammonia, hydrogen, nitrogen and their mixtures, perfluoropolymer membrane technology, membrane and membrane technology of the US Congress, okyo, Japan, 1987:502.
Shi Jun, Zhuangzhen Bay. Lecture on Multiplemembraneparation System. Proceedings of International Symposium Membranes and Membereparation Processes. Main, Torun, Poland, 1989:33.
3 Lu Xiaohua, Wang Yanru, Shi Jun. Prediction of vapor-liquid equilibrium of salt solution (Ⅰ) Ⅰ) Extension of Pitzer model and its application in multicomponent system. Journal of Chemical Engineering,1989,40 (3): 293
4 Lu Xiaohua, Wang Yanru, Shi Jun. Prediction of vapor-liquid equilibrium of salt solution (Ⅱ) Physical meaning and parameter estimation. Journal of Chemical Engineering,1989,40 (3): 301
Wang Shaokun, Li Jianmin, Shi Jun. Model method. Chromatographic science. 1989，27( 10):596
Li Jianmin, Wang Shaokun and Shi Jun. Flexibility, diversity and symmetry parameters and vapor-liquid equilibrium multicomponent system. Chemical Engineering Science,1990,45 (1):199
No.7, Wanskefeng Road, Shenzhen. Determination of addition constant-gas-liquid chromatography. Chromatogram a.1990,30 (3/4): 211
No.8, Zhuangzhen Bay, Shi Jun. American A 1990 International General Mathematical Model of Diaphragm Pressure and Diaphragm Pressure Process, V 01-Ⅱ:1361
Xu Nanping, Yao Jianmin, Wang Yanru, Shi Jun. Vapor-liquid equilibrium ffivebinarysystems containing r-22. Fluid phase equilibrium, 199 1, 69: 261-270.