For exogenous sandstone-type uranium deposits, whether it is interlayer oxidation zone type or phreatic oxidation (ancient river channel) type, the uranium mineralization process begins with weathering (providing uranium source), and then goes through three stages: migration-precipitation-mineralization; They are all formed in ore-bearing strata by water infiltration and oxidation under the condition of hydrodynamic action, with uranium activation, migration and precipitation enrichment as the main line. Uranium mineralization is characterized by oxidation zone and uranium-bearing zoning, and the formation time of surrounding rock and mineralization is obviously different. The ore bodies are mostly rolled, layered and lenticular.
Uranium in uranium-rich rocks in basement and erosion area is transformed from tetravalent uranium (U4+) to hexavalent uranium (U6+) by weathering and leaching. U6+ combines with oxygen-containing water to form uranyl ion UO2+, which usually migrates in groundwater in the form of uranyl complex. The water quality types are HCO3- type and HCO 3-SO24- type, mainly uranyl carbonate [under the hydrodynamic circulation mechanism,
In the oxygen-deficient part of the oxygen-containing uranium-containing fluid, that is, the front of the oxidation zone, it is the interface between the oxidized rock and the reduced rock, which is the geochemical barrier and the enriched part of precipitation of uranium. There are organic substances such as hydrogen sulfide (H2S), dispersed pyrite (FeS2) and carbon chips in uranium-bearing water, which can destroy and precipitate uranyl complex in uranium-bearing water, and combine iron and sulfur to form pyrite, which will coexist with uranium. In addition, uranium can also be filled in the cell cavity of organic matter. Uranium precipitates and concentrates in this area.
Paleochannel sandstone-type uranium deposits in Erlian basin
In this process, it is restricted by structure-sedimentation, lithology and lithofacies, thus forming uranium deposits of different genesis. For PCSTU deposition, it is the recharge water flowing into the ancient river channel laterally (valley slope) or along the river channel direction or vertically ("skylight") to the discharge water flowing out of the ancient river channel. The process is that under the hydrodynamic conditions of the ancient river, the infiltration water containing uranium and oxygen interacts with the ore-bearing sandstone to form structural-sedimentary evolution and lithology-rock.