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Inquiring the classification of chemical products by CAS number; organic raw material carboxylic acid compounds and their derivatives carboxylic acid esters and their derivatives 2- ethylhexyl acrylate (2-EHA)
2- ethylhexyl acrylate (2-EHA)
Updated: 2022-01-120: 07:11.
Structural formula of 2- ethylhexyl acrylate (2-EHA)
Structural formula of 2- ethylhexyl acrylate (2-EHA)
Common name 2- ethylhexyl acrylate (2-eha) English name 2-ethyl acrylic.
CASNo. 103- 1 1-7 Molecular Weight 184.275
At 760mmhg, the density is 0.9 0.1g/cm3, and the boiling point is 216.0 0.0 degrees Celsius.
The molecular formula c 1 1h2o 2 melting point -90? C
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Chinese version
American edition
Flash point 79.4 0.0℃
Symbol GHS07
GHS07 signal word warning
Brand specification purity membership price operation
Ron 5ml 99.5% (analytical standard reagent) ￥ 190.00 ￥ 152.00.
Maclean 5ml analytical standard, ≥ 99.5% (GC) ￥ 220.00176.00.
Aladdin 5ml analytical standard ≥ 99.5% (GC) ￥ 227.00182.00.
* If you have other special requirements on prices and specifications, please contact online customer service.
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Use 2- ethylhexyl acrylate (2-EHA)
Used as internal plasticization in polymerization monomers, soft polymers and * * * polymers.
Product nature
Literature review 33
Illustration set
Name of 2- ethylhexyl acrylate (2-EHA)
Chinese name 2- ethylhexyl acrylate
English name 2- ethylhexyl acrylate
Chinese alias-2- ethylhexyl acrylate
More English aliases
Physical and chemical properties of 2- ethylhexyl acrylate (2-EHA)
Density 0.9 0. 1 g/cm3/cm3
Boiling point: 216.0 0.0℃ at 760mmhg.
Melting point -90? C
The molecular formula is c 1 1h2o2.
Molecular weight 184.275
Flash point 79.4 0.0℃
Accurate mass 38880.48886861
PSA 26.30000
LogP 4.33
Appearance characteristics colorless liquid
Vapor density 6.4 (relative to air)
The vapor pressure at 25℃ is 0. 1.4 mm Hg.
Refractive index 1.434
Storage conditions are stored in a cool and ventilated warehouse. Stay away from fire and heat sources. Keep away from light. The reservoir temperature should not exceed 30℃. Keep the container sealed, and it is forbidden to contact with air. Should be stored separately from oxidant, acid and alkali, and should not be mixed. Equipped with corresponding varieties and quantities of fire fighting equipment. The storage area should be equipped with emergency response equipment for leakage and suitable accommodation materials. Storage temperature 2-8? C
stability
1. Light polymerizes easily. Avoid contact with strong oxidants, strong acids and strong bases. Flammable, flammable in case of open flame and high heat.
2. It exists in mainstream smoke.
3. Sensitive to light, tears.
water-solubility
molecular structure
1, molar refractive index: 54.46
2. Molar volume (cc/mol): 209.0
3. Isotonic specific volume (90.2 k): 480.9
4. Surface tension (dyne/cm): 27.9
5. Dielectric constant:
6. Dipole distance (10-24cm3):
7. Polarization: 2 1.59
computational chemistry
1. Reference value for calculation of hydrophobic parameters (XlogP):3.8.
2. Number of hydrogen bond donors: 0
3. Number of hydrogen bond acceptors: 2
4. Number of rotatable chemical bonds: 8
5. Number of tautomers: None
6. Polar surface area of topological molecules 26.3
7. Number of heavy atoms: 13
8. Surface charge: 0
9. Complexity: 152
10. Isotope number: 0
1 1. Determine the number of atomic solid centers: 0.
12. The number of uncertain atomic solid centers: 1.
13. Determine the number of solid centers of chemical bonds: 0.
14. Number of uncertain chemical bond solid centers: 0.
15.*** Number of valence bond units: 1
more
1. Description: Colorless and transparent liquid, odorless and tasteless.
2. Density (g/ml, 20/4℃): 0.8845
3. Relative steam density (g/ml, air = 1): 6.35.
4. Melting point (? C):-90
5. Boiling point (? C): 123~ 127(7998pa)
6. Refractive index (n20? C): 1.4365
7. Viscosity (MPa sec, 20? C): 1.54
8. Flash point (open cup,? C):86
9. Autoignition point or ignition temperature (? C): 252
10. vapor pressure (mmHg, 20? C):0. 15
Steam pressure (kPa, 20? C):0.02
12. heat of vaporization (kj/mol): 47.0.
13. Upper explosion limit (%), v/v:6.4.
14. Lower explosion limit (%), v/v): 0.9.
15. solubility: miscible with ethanol and ether, slightly soluble in water.
16. liquid standard hot melt (j mol- 1 k- 1): 380.8.
2- ethylhexyl acrylate (2-EHA)MSDS
Part I: Names of Chemicals
Chemical Chinese name: 2- ethylhexyl acrylate
English name of chemical: 2-ethylhexyl acrylate; 2- ethylhexyl acrylate
Chinese common name or trade name:
Synonym:
CASNo.: 103- 1 1-7
Molecular formula: c 1 1h2o 2.
Molecular weight: 184 438+0
Part II: Composition/Composition Information
Pure chemical mixture
Chemical name: 2- ethylhexyl acrylate
Content of harmful substances, CAS number
2- ethylhexyl acrylate100103-11-7
The third part: risk overview.
Hazard category:
Invasion route: inhalation, ingestion and percutaneous absorption.
Health hazard: this product has irritating effect on skin and eyes. It belongs to low toxicity, but it will be poisoned if inhaled, ingested or absorbed through the skin. Speaking of heat, it explains the irritating smoke.
Environmental hazards:
Danger of explosion: This product is flammable and irritating.
Part IV: First aid measures
Skin contact: rinse thoroughly with soapy water and clean water. See a doctor.
Eye contact: Open eyelids and rinse with running water 15 minutes. See a doctor.
Inhalation: leave the scene quickly and go to a place with fresh air. Keep the respiratory tract unobstructed. If you have difficulty breathing, give oxygen. If breathing stops, give artificial respiration immediately. See a doctor.
Ingestion: If taken by mistake, drink proper amount of warm water to induce vomiting. See a doctor.
Part V: Fire Prevention Measures
Hazard characteristics: flammable in case of open fire and high heat. Contact with strong oxidants will lead to chemical reactions. Its vapor is heavier than air, and it can spread to a considerable distance at a lower place, and it will catch fire when it meets a fire source. It is easy to self-polymerize, and the polymerization reaction increases rapidly with the increase of temperature. In case of high heat, the internal pressure of the container rises, which is in danger of rupture and explosion.
Harmful combustion products: carbon monoxide and carbon dioxide.
Fire extinguishing methods and extinguishing agents: atomized water, insoluble foam, carbon dioxide, dry powder.
Personal protection of firefighters: Firefighters must wear gas masks and full-body fire protection suits to put out fires in the upwind direction.
Prohibit fire extinguishing agent:
Flash point (℃): 75.80
Autoignition temperature (℃): 252
Lower explosion limit [%(v/v)]: 0.8
Upper explosion limit [%(v/v)]: 6.4
Minimum ignition energy (mJ):
Deflagration point:
Explosion speed:
Maximum explosion pressure (MPa):
Classification of building codes and fire risks;
Part VI: Emergency treatment of leakage.
Emergency treatment: evacuate the personnel in the leaked contaminated area to a safe area, and prohibit irrelevant personnel from entering the contaminated area. It is recommended that emergency personnel wear self-contained breathing apparatus and chemical protective clothing. Mixed with sand, dry lime or soda ash, collected in a closed container and transported to the waste disposal site. It can also be scrubbed with emulsion made of incombustible dispersant. If a large amount of leakage occurs, it will be contained by the dike, and then collected, transferred, recycled or discarded after harmless treatment.
Part VII: Operation, Disposal and Storage
Precautions for operation: closed operation, local exhaust. Prevent the steam in the workplace from leaking into the air. Operators must be specially trained and strictly abide by the operating procedures. Operators are advised to wear self-priming filter gas mask (half mask), chemical safety glasses, anti-static work clothes and rubber gloves. Stay away from kindling and heat sources, and smoking is strictly prohibited in the workplace. Use explosion-proof ventilation system and equipment. Welding, cutting and other operations are not allowed before liquid and steam are removed. Avoid producing smoke. Avoid contact with oxidants, acids and bases. Containers and transmission equipment should be grounded to prevent static electricity. When filling, the flow rate should be controlled, and grounding devices should be provided to prevent static electricity accumulation. Equipped with corresponding varieties and quantities of fire fighting equipment and leakage emergency treatment equipment. Empty containers may leave harmful substances behind.
Precautions for storage: Store in a cool and ventilated warehouse. Stay away from fire and heat sources. Keep away from light. The reservoir temperature should not exceed 30℃. Keep the container sealed, and it is forbidden to contact with air. Should be stored separately from oxidant, acid and alkali, and should not be mixed. Equipped with corresponding varieties and quantities of fire fighting equipment. The storage area should be equipped with emergency response equipment for leakage and suitable accommodation materials.
Part VIII: Contact Control/Personal Protection
Maximum allowable concentration: China MAC: former Soviet MAC: United States TLV—TWA: standard not formulated.
Monitoring method:
Engineering control: the production process is sealed and ventilation is strengthened.
Respiratory system protection: When the concentration in the air exceeds the standard, you must wear a self-priming filter gas mask (half mask). Air respirator should be worn during emergency rescue or evacuation.
Eye protection: Wear safety glasses.
Physical protection: wear anti-static work clothes.
Hand protection: wear rubber gloves.
Other protection: Smoking and eating are prohibited in the workplace. Take a shower and change clothes after work. Pay attention to personal hygiene.
Part IX: Physical and Chemical Characteristics
Colorless liquid.
PH value:
Melting point (℃):-90
Boiling point (℃): 2 15-2 19.
Relative density (water = 1): 0.8869 (20℃)
Relative steam density (air = 1): 6.35.
Saturated vapor pressure (kpa): 0.02/20℃
Heat of combustion (kJ/mol):
Critical temperature (℃):
Critical pressure (MPa):
Logarithmic value of octanol/water partition coefficient:
Flash point (℃): 75.80
Ignition temperature (℃): 252
Upper explosive limit% (volume/volume): 6.4
Lower explosive limit% (volume/volume): 0.8
Molecular formula: c 1 1h2o 2.
Molecular weight: 184 438+0
Evaporation rate:
Stickiness:
Solubility: Insoluble in water, soluble in most organic solvents.
Main uses: used for manufacturing coatings, adhesives, fiber and fabric modification, processing AIDS, leather processing AIDS, etc.
Part X: Stability and Reactivity
Stability: unstable at normal temperature and pressure.
Prohibited compounds: strong oxidants, strong acids and strong bases.
Conditions to avoid contact: light is easy to polymerize.
Aggregation danger: it may happen.
Decomposition products: carbon monoxide and carbon dioxide.
Part XI: Toxicological data
Acute toxicity: LD500: 5600 mg/kg (taken orally by rats); LC50 of 7539 mg/kg (rabbit skin): No data available.
Acute poisoning:
Chronic poisoning:
Subacute and chronic toxicity:
Irritation: rabbit percutaneous: 20mg/24 hours, moderate irritation. Percutaneous rabbit: open stimulation test, 500mg, mild stimulation. Rabbit eye: 5mg, severely irritating. Rabbit eyes: 500mg/24 hours, mild irritation.
Sensitization:
Mutagenicity:
Teratogenicity:
Carcinogenicity:
Part XII: Ecological data
Eco-toxicological toxicity:
Biodegradability:
Non-biodegradable:
Bioaccumulation or bioaccumulation:
Part XIII: Abandonment and Disposal
Nature of waste:
Disposal method of waste: it is suggested to control incineration or safely bury it. If possible, reuse the container or bury it in a designated place.
Abandoned preventive measures:
Part XIV: Transportation Information
Dangerous goods number:
United Nations number:
Packaging mark:
Packaging category:
Packing method: No data.
Precautions for transportation: Check whether the packaging container is complete and sealed before transportation to ensure that the container does not leak, collapse, fall or be damaged during transportation. It is forbidden to mix with oxidant, acid, alkali and edible chemicals. Transport vehicles and boats must be thoroughly cleaned and disinfected, otherwise other items may not be shipped. During shipment, the assembly position should be far away from the bedroom and kitchen, and isolated from the engine room, power supply, fire source and other parts. Highway transportation should follow the prescribed route.
RETCS number:
IMDG rule page number:
Part XV: Regulatory Information
Domestic regulations on chemical safety management: Regulations on Safety Management of Hazardous Chemicals (promulgated by the State Council on February 7, 1987), Detailed Rules for the Implementation of Regulations on Safety Management of Hazardous Chemicals (Hua Laofa [1992] No.677) and Regulations on Safe Use of Chemicals in Workplaces (1996] No.423).
International Regulations on Chemical Safety Management:
Part XVI: Other Information
References: 1. Zhou Guotai, Encyclopedia of Safety Technology of Hazardous Chemicals, Chemical Industry Press, 1997 2. Toxic Chemicals Management Office of State Environmental Protection Agency, Beijing Institute of Chemical Technology, Environmental Data Manual of Chemical Toxicity Regulations, China Environmental Science Press. 1992 3. Canadian occupational health and safety center, Cheminfo database. 1998 4。 Canadian occupational health and safety center, RTECS database, 1989.
Time to fill in the form: year month day.
Filling department:
Data audit unit:
Version description:
Other information: 5
MSDS Revision Date: Year Month Day
Toxicity and ecology of 2- ethylhexyl acrylate (2-EHA)
Toxicological data of 2- ethylhexyl acrylate (2-EHA);
1, irritation: rabbit skin: 20mg/24h, moderately irritating. Percutaneous rabbit: open stimulation test, 500mg, mild stimulation. Rabbit eye: 5mg, severely irritating. Rabbit eyes: 500mg/24 hours, mild irritation.
2. Acute toxicity: oral LD50: 5600 mg/kg in rats; Rabbit percutaneous LD50: 7539 mg/kg
3. Irritating to eyes, respiratory system and skin.
Ecological data of 2- ethylhexyl acrylate (2-EHA);
This substance is slightly harmful to water.
Toxicity of 2- ethylhexyl acrylate (2-EHA)
Safety information of 2- ethylhexyl acrylate (2-EHA)
Symbol GHS07
GHS07
Signal word warning
Hazard statement h 315-h 317-h335-h 412
Warning statement p273-p280-p304+p340+p312-p333+p313.
Personal protective equipment goggles; Mask; Full-face respirator (USA); Gloves; Multi-purpose combined respirator filter element (USA); ABEK respirator filter (EN 14387)
Hazard code (Europe) Xi: Irritation
Risk statement (Europe) R37/38；; R43
Safety Statement (Europe) S36/37-S46
Dangerous goods transport code UN3334 9
Germany WGK 1
RTECS number AT0855000
Customs code 29 16 1290
2- ethylhexyl acrylate (2-EHA) composite wire
2-ethyl hexanol structural formula
2-ethyl hexanol
104-76-7
Acrolein structural formula
acrolein
107-02-8
~%
Structural formula of 2- ethylhexyl acrylate (2-EHA)
2- ethylhexyl acrylate (2-EHA)
103- 1 1-7
Literature: us2003/216587a1; Page 3-4/Column 4;
2-ethyl hexanol structural formula
2-ethyl hexanol
104-76-7
Acrylic structural formula
acrylic acid
79- 10-7
~%
Structural formula of 2- ethylhexyl acrylate (2-EHA)
2- ethylhexyl acrylate (2-EHA)
103- 1 1-7
Literature: us 2917538;
Unregistered structural formula
Not logged in
500790-28-3
~%
Structural formula of 2- ethylhexyl acrylate (2-EHA)
2- ethylhexyl acrylate (2-EHA)
103- 1 1-7
Literature: Journal of American Chemical Society, Volume 67, Page 57.
Upstream and downstream products of 2- ethylhexyl acrylate (2-EHA)
Upstream product of 2- ethylhexyl acrylate (2-EHA) 5
2-ethyl hexanol Structural Chemical Abstracts AgencyNo. 104-76-7
2-ethyl hexanol
Acrolein Structural Chemical Abstracts AgencyNo. 107-02-8
acrolein
Chemical abstracts service of acrylic acid structural formula No.79-10-7
acrylic acid
Acetylene structural chemical abstracts service number 74-86-2
acetylene
2- ethylhexyl acrylate (2-EHA) downstream product 5
Octyl p-methoxycinnamate structural formula CAS No.5466-77-3
Octyl p-methoxycinnamate
The structural formula of 2- ethylhexyl 3-(4- bromophenyl) sulfinylpropionate is CAS No.88 1664-08-0.
3-2- ethylhexyl ...
Propionic acid, 2- ethylhexyl ester, structural formula is CAS No.6293-37-4.
Propionic acid, ...
Bis -(2- ethyl-hexyl ester) of 4- oxo-heptanedioic acid has the structural formula CASNo. 8 1733-97-3.
4- oxoheptylene ...
Preparation of 2- ethylhexyl acrylate (2-EHA)
1. Acrylic acid and 2-ethyl hexanol were directly esterified with sulfuric acid as catalyst, then neutralized, dealcoholized and rectified to obtain the finished product.
103- 1 1-7 preparation
2. Ester exchange method Methyl acrylate and 2-ethyl hexanol were subjected to ester exchange reaction in the presence of titanium tetrachloride catalyst to produce 2- ethylhexyl acrylate, and the finished product was obtained by rectification.
3. Methyl acrylate and 2- ethyl ethanolamine were mixed according to the molar ratio of 3∶ 1, and the gas phase transesterification reaction was carried out at 227 ~ 228℃. The conversion rate was 32% and the yield was 97%. When transesterification is carried out in liquid phase, the yield is 70% ~ 80%.
4. Add a certain amount of acrylic acid, isooctyl alcohol, catalyst (SO42-/ZrO _ 2) and inhibitor phenothiazine into the reaction kettle, and heat and reflux until there is no water to precipitate. The reaction liquid was washed with alkali and water until it was neutral, and then distilled under reduced pressure to collect the product. The amount of catalyst is 5% of the mass of acrylic acid, the amount of polymerization inhibitor is 0.05% of the mass of acrylic acid, the ratio of raw material (isooctyl alcohol) to acrylic acid is = 1.2: 1, the reaction temperature is 120℃, and the reaction time is 3h.
Customs of 2- ethylhexyl acrylate (2-EHA)
Customs code 29 16 129000
English abstract 29 16 129000 Other acrylates. VAT rate: 17.0% Tax rebate rate: 9.0% Regulatory conditions: no MFN tariff: 6.5% General tariff: 30.0%.
The name, content and use of the declared elements, as well as the packaging of acrylic acid, acrylate or ester shall be stated.
Summary 29 16 129000 VAT on other acrylic esters: 17.0% Tax rebate rate: 9.0% Regulatory conditions: no MFN tariff: 6.5% General tariff: 30.0%.
2- ethylhexyl acrylate (2-EHA) literature 33 more literature
Development and application of non-targeted extraction method for analyzing migrating compounds in plastic bottles by GC-MS
Food additives. Contaminants. The chemistry section. Anal. Control. World Expo. Risk assessment. 3 1( 12) , 2090- 102, (20 14)
20 1 1 year, due to the toxic effect of bisphenol A, the European Union banned the production of polycarbonate (PC) baby bottles. Therefore, baby bottles made of alternative materials, ...
detail
Nuclear magnetic resonance spectroscopy was used to predict the reduced glutathione (GSH) reactivity of dental methacrylate monomers-the relationship between toxicity and GSH reactivity.
Dent. Mater Judicial Reports, vol. 28, No.6, pp. 722-9 (2009)
It has been determined that the toxicity of acrylate and methacrylate monomers is driven by their reactivity to glutathione (GSH). According to this relationship, the purpose of this study is to predict. ...
detail
Potential irritation of residual (meth) acrylic monomer in pressure-sensitive adhesive tape to skin.
Medicinal chemistry. Poison. 33( 1) , 1-7, (20 10)
It is generally believed that the common residual unpolymerized (meth) acrylic monomer in medical pressure-sensitive adhesive tapes may cause skin irritation, but a systematic study found that. ...
detail
English alias of 2- ethylhexyl acrylate (2-EHA)
Ethoxy -2- ethyl acrylate
2- ethyl -65438+ 0- hexyl acrylate
2- ethylhexyl acrylate monomer
UNII-HR49R9S6XG
2- ethylhexyl 2- acrylate
2- ethylhexyl acrylate
2- ethyl
2-ethyl hexanol acrylate
2- ethylhexyl acrylate
MFCD00009495
2- ethylhexyl acrylate
2- ethylhexyl acrylate
Octyl acrylate monomer
Ethylhexyl acrylate
2- ethylhexyl acrylate (2-EHA)
Mono (2- ethylhexyl) acrylate
2- ethylhexyl propyl -2- enoate
2- ethylhexyl acrylate
EINECS 203-080-7
Octyl acrylate monomer
Octyl acrylate
2- ethylhexyl 2- acrylate
2- ethylhexyl acrylate
2-EHA
Ethyl -2- hexyl acrylate
65438+2-ethyl hexanol acrylate
2-ethvlhexlavlate
O-2- ethylhexyl acrylate
2- ethylhexyl acrylate
2- ethylhexyl acrylate monomer
Ethylhexyl acrylate (ethyl hexyl acrylate)
Brand spot direct purchase
Related compounds: more ...
2 ethylhexyl acrylate
29590-42-9
Polymer of 2-2- ethylhexyl acrylate and 2- acrylamide
50922-82-2
Polymer of 2-2- ethylhexyl acrylate and N-( 1, 1, 3,3-tetramethylbutyl) -2- acrylamide.
70069-8 1-7
2- cyano-3,3-diphenyl-2- ethylhexyl acrylate
6 197-30-4
Polymer of 2-2- ethylhexyl acrylate and acrylic acid
90 17-68-9
iso octyl methacrylate
28675-80- 1
3- phenyl 2- ethylhexyl acrylate
16397-78-7
α-cyano-2- ethylhexyl acrylate
184765-00-2
* * * Polymer of acrylic acid, 2- ethylhexyl acrylate and vinyl acetate.
6625 1-44-3
Recommended supplier:
Nantong Feng Run Petrochemical Co., Ltd.
Chongchuan District, Nantong City, Jiangsu Province
Product name: 2- ethylhexyl acrylate
Purity: 99.5%
Lead time: 1 day
Contact: Cao Haibing
Tel: 176254398 17
Shanghai jizhi biochemical technology co., ltd
Fengxian District, Shanghai, China
Product name: 2- ethylhexyl acrylate
Purity: 99.0%
Lead time: need to query.
Contact: Wang Xiaoyan
Tel: 189 17409608
Wuhan Fengtai Weiyuan technology co., ltd
Hongshan District, Wuhan city, Hubei province
Product name: 2- ethylhexyl acrylate
Purity: 98.0%
Lead time: need to query.
Contact: Miss Yang
Tel:18971372418.
Shanghai chuangsai technology co., ltd
Shanghai Jiading District Shanghai
Product name: [Perfemiker] 2- ethylhexyl acrylate, > 99.0%(GC), containing MEHQ stabilizer.
Purity: 99.0%
Lead time: 1 day
Contact: Ling Du
Tel: 17302 163957
Shanghai Aladdin biochemical technology co., ltd.
Shanghai Pudong New Area, Shanghai
Product name: 2- ethylhexyl acrylate (2-EHA)
Purity: 99.0%
Lead time: 1 day
Contact: Aladdin
Tel:18521732815.
Zhongshan Di Xin chemical co., ltd
Sanjiao Town, Zhongshan City, Guangdong Province
Product name: 2- ethylhexyl acrylate
Purity: 99.0%
Delivery time: 3 days
Contact: Wang Jie
Tel: 1893390325
Shandong jinyueyuan new material co., ltd
Tianqiao district, Ji 'nan City, Shandong Province
Product name: octyl (iso) acrylate
Purity: 99.5%
Delivery time: 3 days
Contact: Wang Sibing
Tel:18615186228.
Ji' nan century Tongda chemical co., ltd
Tianqiao district, Ji 'nan City, Shandong Province
Product name: 2- ethylhexyl acrylate
Purity: 99.5%
Lead time: 1 day
Contact: Manager Wang
Tel: 1509895 1629
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