The reaction and mechanism of organic names is a book published by East China University of Science and Technology Press in September 2003 1. The author is Li Jie (USA).
This book selects 33 1 organic names. Each reaction gives a step-by-step detailed electron transfer mechanism and related original and latest references, including 2003. Many of the more than 2740 references listed in the book are summary papers, which help readers to better understand and recognize organic reactions and facilitate the in-depth application of organic reactions.
To some extent, organic chemistry is a characteristic subject that is highly dependent on individual creativity and has been constantly innovating and developing. Its progress also lies in the development or application of new reactions discovered or invented by many great organic chemists over the past 200 years.
In the development of modern organic chemistry, people have become accustomed to naming these new reactions with the names of chemists who discovered or invented them, that is, "named reactions", which is translated as "named reactions" in Chinese.
1. Arbuzov (Arbuzov) reaction-alcohol and phosphorus trihalide generate trialkyl phosphite, and then exchange alkyl groups with halogenated hydrocarbons.
2.? Arndt-Eistert (arndt-Esther) reaction-diazomethane reacts with acyl chloride in the presence of silver oxide and water to produce polycarboxylic acids.
3.? Bayer-Wiley thermal oxidation-oxidation of ketones and peroxyacids, resulting in rearrangement of esters.
4.? Beckmann rearrangement-rearrangement of oxime and sulfuric acid into amide.
5.? Birch reduction reaction-aromatic ring is reduced to unconjugated hexadiene by alkali metal in liquid ammonia and alcohol.