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How to change benzene into p-nitrobenzoic acid in university organic chemistry
Firstly, toluene was synthesized by F-C alkylation (using CH3Cl+AlCl3), then nitration (this can be controlled in para position), and finally methyl group was oxidized to carboxyl group.

If nitration is carried out first, it is equivalent to introducing a passivation group on the benzene ring, so it is difficult to introduce methyl.