About the author:
Works: Physical Chemistry Volume I, Physical Chemistry Volume II, University Chemistry (Volume II), University Chemistry (Volume I), Physical Chemistry (Volume V), Physical Chemistry-(Volume IV) (Volume II)
Book Introduction
0. 1 Establishment and development of physical chemistry
O.2 Purpose and content of physical chemistry
0.3 Physical and chemical research methods
O.4 learning methods of physical chemistry course
Extracurricular reference books
Chapter I Qi
1. 1 gas molecular dynamics theory
Basic formula of gas molecular dynamics theory
Statistical concepts of pressure and temperature
Explaining several empirical laws with gas molecular motion formula
Relationship between molecular average translational energy and temperature
1.2 molar gas constant (r)
1.3 state diagram of ideal gas
Velocity distribution of 1.4 molecular motion
Maxwell's law of velocity distribution
Derivation of Maxwell's velocity distribution function
Three statistical averages of molecular velocity-most probable rate, mathematical average rate and root mean square rate.
Verification of gas molecular distribution based on rate-molecular beam experiment
The translational energy distribution of 1.5 molecule
1.6 distribution of gas molecules in gravity field
Collision frequency and average free path of 1.7 molecule
Mean free path of molecules
Molecular collision frequency
Collision frequency between molecules and equipment walls
Molecular interstitial flow
1.8 actual gas
Behavior of actual gas
van der waals equation
Other equations of state
1.9 transition between gas and liquid-isotherm and liquefaction process of actual gas
Isotherms of gases and liquids
Isothermal Currency of Van der Waals Equation
Contrast state and law of contrast state
1. 10 compressibility diagram-calculation of actual gas
1. 1 1 intermolecular interaction force
Basic requirements of this chapter
Extracurricular reference books
Review exercises
utilize
Chapter II First Law of Thermodynamics
2. 1 Introduction to Thermodynamics
Basic contents of thermodynamics
Methods and limitations of thermodynamics
2.2 thermal balance and the zeroth law of thermodynamics-the concept of temperature
2.3 Some basic concepts of thermodynamics
System and environment
Properties of the system
Thermodynamic equilibrium state
State function
state equation
Process and method
Heat and work
2.4 the first law of thermodynamics
2.5 Quasi-static process and reversible process
Work and process
quasistatic process
reversible process
2.6 enthalpy
2.7 heat capacity
2.8 Application of the First Law of Thermodynamics to Ideal Gas
Thermodynamic Energy and Enthalpy of Ideal Gas Cap-Lussac