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Works: Physical Chemistry Volume I, Physical Chemistry Volume II, University Chemistry (Volume II), University Chemistry (Volume I), Physical Chemistry (Volume V), Physical Chemistry-(Volume IV) (Volume II)

Book Introduction

0. 1 Establishment and development of physical chemistry

O.2 Purpose and content of physical chemistry

0.3 Physical and chemical research methods

O.4 learning methods of physical chemistry course

Extracurricular reference books

Chapter I Qi

1. 1 gas molecular dynamics theory

Basic formula of gas molecular dynamics theory

Statistical concepts of pressure and temperature

Explaining several empirical laws with gas molecular motion formula

Relationship between molecular average translational energy and temperature

1.2 molar gas constant (r)

1.3 state diagram of ideal gas

Velocity distribution of 1.4 molecular motion

Maxwell's law of velocity distribution

Derivation of Maxwell's velocity distribution function

Three statistical averages of molecular velocity-most probable rate, mathematical average rate and root mean square rate.

Verification of gas molecular distribution based on rate-molecular beam experiment

The translational energy distribution of 1.5 molecule

1.6 distribution of gas molecules in gravity field

Collision frequency and average free path of 1.7 molecule

Mean free path of molecules

Molecular collision frequency

Collision frequency between molecules and equipment walls

Molecular interstitial flow

1.8 actual gas

Behavior of actual gas

van der waals equation

Other equations of state

1.9 transition between gas and liquid-isotherm and liquefaction process of actual gas

Isotherms of gases and liquids

Isothermal Currency of Van der Waals Equation

Contrast state and law of contrast state

1. 10 compressibility diagram-calculation of actual gas

1. 1 1 intermolecular interaction force

Basic requirements of this chapter

Extracurricular reference books

Review exercises

utilize

Chapter II First Law of Thermodynamics

2. 1 Introduction to Thermodynamics

Basic contents of thermodynamics

Methods and limitations of thermodynamics

2.2 thermal balance and the zeroth law of thermodynamics-the concept of temperature

2.3 Some basic concepts of thermodynamics

System and environment

Properties of the system

Thermodynamic equilibrium state

State function

state equation

Process and method

Heat and work

2.4 the first law of thermodynamics

2.5 Quasi-static process and reversible process

Work and process

quasistatic process

reversible process

2.6 enthalpy

2.7 heat capacity

2.8 Application of the First Law of Thermodynamics to Ideal Gas

Thermodynamic Energy and Enthalpy of Ideal Gas Cap-Lussac