2 National Collection of Chinese Herbal Medicine: Snake Containing Stone 2. 1 Pinyin name Shé Hán Shí
2.2 snake yellow, alias of stone snake.
2.3 Nodules from limonite. Clear the soil.
2.4 The shape is slightly spherical or irregular rectangle, with different sizes and a diameter of about 0.7 ~ 3 cm. Brown or dark brown, rough surface, uneven, covered with a layer of powder. Hard, not easy to crush, yellow-white section with metallic luster, similar to native copper, yellow-white section center with metallic luster (pyrite), dark brown or dark brown edge, and yellowish brown and silty (limonite) outermost layer. A slight breath, a faint taste.
2.5 Sexual taste is sweet and cold.
2.6 Function is mainly used for spasmolysis and pain relief. Used for convulsion, epilepsy and joint pain.
2.7 usage and dosage include stone snake 1 ~ 3 money.
2.8 Remarks (1) Tuzi in a few areas is falsely filled with snakes and contains stones. Although the external washing of the two is similar, the snake is heavy and difficult to crush, while the anonymous is light, fragile and easy to crush. The two should not be confused.
2.9 Excerpted from the National Compilation of Chinese Herbal Medicine
3 Chinese Materia Medica and Dictionary of Traditional Chinese Medicine: Snakes contain stones 3. 1 From Compendium of Materia Medica.
3.2 Pinyin name Shé Hán Shí
3.3 English name Limonite
3.4 Stone-bearing snakes are nicknamed Snake Yellow and Snake Yellowstone.
3.5 Source: oxidized mineral limonite nodules.
Latin animal and plant mineral name: pyrite; brown iron ore
Harvest and storage: remove soil impurities after harvest.
3.6 Original Form 1. Pyrite crystal structure belongs to equiaxed crystal system; White iron ore with the same composition and belonging to orthogonal crystal system; These two species are homogeneous polymorphs, both of which are FeS2. Nodules, crystal competition or fine-grained individuals are arranged radially and have a concentric ring structure. The fresh surface is light brass with metallic luster, with hardness of 66.5 and relative density of 4.95.2. Weathered surface is purplish brown or brownish yellow, with earthy luster, reduced hardness and relative density. The hardness of white iron ore is 56 and the relative density is 4.9. Hard and brittle, uneven section. Limonite with weathered surface, with brown or yellowish brown cross-section edges and the same core as pyrite (or white iron ore).
2. Limonite, amorphous. Often into grape-shaped, kidney-shaped, * * * shaped, massive, earthy and other aggregates. The color is brownish black, while khaki is tan or yellow. The stripes are yellowish brown. Semimetallic or earthy luster, sometimes silky luster. Opaque. The cross section is shell-shaped or soil-shaped. Hardness 15.5. Specific gravity 3.64.0.
3.7 Ecological environment of habitat distribution: 1. It mainly exists in the oxidation zone of sedimentary rocks and metal minerals.
2. It is mainly formed by oxidation and decomposition of iron-containing minerals, followed by hydrolysis, collection and deposition.
Resource distribution: 1. Produced in Shanxi, Jiangsu, Zhejiang, Henan, Guangdong, Sichuan and other places.
2. The main producing areas are Hebei, Jiangsu, Zhejiang and Henan.
3.8 Character identification This product is a granular or tuberculous aggregate. It is spherical, oval or irregular. Diameter 1.54.5cm brownish yellow or brown. Rough surface, dense cubic protrusions, often covered with a layer of dark yellow powder. Weight, hard mass. The cross section is radial or concentric ring; External color; Deep production, brown or brownish yellow (part of limonite); Earthy luster. The central nuclear layer is light in color, with copper yellow, light yellow or grayish yellow (pyrite part) and metallic luster. It has a slight sulfur smell and a light taste.
Microscopic observation under reflective polarizer: light brass color. Spherical aggregates are common in cross polarizers, and the spherulites are about 0.06mm in diameter and often filled in cavities. Therefore, the observation of reflected light shows that nodules can be roughly divided into colloidal pyrite and microcrystalline spherulite. The former is often distributed in cavities or cracks. Iron oxide is still visible in the fracture, and pyrite is isotropic.
White iron ore reflectivity: visual value: green: 52; Orange: 45.25; Red: 44.5. The double reflection is clear and strongly uneven, and the spherical particles are parallel and cross-extinction.
The surface layer of pyrite nodules of limonite has weathered into limonite; The reflected light is red or brown. The interior is often pyrite or white iron ore with the same characteristics as above.
3.9 Limonite is mainly composed of hydrated iron oxide (2Fe2O3 3H2O), with impure quality and uncertain water content, and often mixed with impurities such as sand, clay, manganese, phosphorus, calcium and vanadium. Pyrite mainly contains iron sulfide (FeS2).
3. 10 Identification (1) Take 0.2g of this product powder, add 10ml of dilute hydrochloric acid, shake well, filter, and test the filtrate as follows: ① Take 2ml of filtrate, and add potassium ferrocyanide test solution dropwise to generate dark blue precipitate; Separation, the precipitate is insoluble in dilute hydrochloric acid, but it is decomposed into brown precipitate by adding sodium hydroxide test solution. (Check the iron salt) ② Take 2ml of filtrate and add ammonium thiocyanate test solution dropwise, which is blood red. (Check the iron salt) (2) The curve characteristics of X-ray diffraction analysis show that the crude product is mainly composed of pyrite, 4.22 (4), 3. 14 (2), 2.72 (10) and 2.43 (5). After forging, it is transformed into hematite, 3.72 (2), 2.7 1 (140), 2.53 (8).
(3) The differential thermal analysis curve shows that the heat absorption of the crude product is 365438 09℃ (small). 390℃ (micro), 6 10℃ (large), 665℃ (micro); Exothermic 705℃ (small). There was slight weight gain between 0 130℃, and weight loss after 130390℃, 3906 10℃ and 670℃.
3. 1 1 Clean the soil and mash it into small pieces. "Japanese Herbal Medicine": Red-burned three or four times and quenched with vinegar, used for flight research.
3. 12 sweet; cold
3. 13 enters the pericardium; Liver meridian
3. The function of14 is mainly used to soothe the nerves and stop spasms; Stop bleeding and relieve pain. Main palpitations, convulsions and epilepsy; Intestinal wind and blood dysentery; Stomach pain; Carbuncle, sore, swelling and poison; arthralgia
3. 15 usage and dosage of stone snake: decoction, 23 yuan; I still took the pills and dispersed them. External use: grinding and application.
3. 16 attachment ① flustered fire treatment: snake yellow (burning red, wine quenching until crisp), cinnabar (flying with snake yellow), gastrodia elata (not last). Mix the three flavors evenly, half a dollar each, less mint soup, and lie down after eating at night. ("Materia Medica Yi Yan") 2 Treatment of wind epilepsy, regardless of age, is formed by accumulating hot air and phlegm: 20 small snakes, mixed with oak juice, red in the fire, taken out, washed on the ground overnight, finely ground into flour; Use another kind of dog gall, take juice and mix it with corn rice and pills, which is as big as mung beans. Take fifteen capsules with warm wine every time, and spit out bad phlegm after three or five days. (Sheng Huifang) (3) Treating infantile convulsion epilepsy, because of panic, the name is trance: snake Huang San (true, quenched with fire vinegar), turmeric seven points (one for the end), musk. The top is the bottom, and the rice ball is big. Take one or two tablets at a time, stir-fry gold and silver, sharpen the knife and hydrate. ("Children's Medicine Syndrome" Shehuang Pill) ④ Treating intestinal wind and blood: two Shehuang Pills, calcined, quenched with vinegar for seven times, and ground into flour. Every time you take San Qian Bi, Laomi drinks it before eating. ("Sheng Ji Zong Lu" shoots Huang San)
3. 17 Various expositions 1. "Primitive Elements": Snakes contain stones, which are naturally not far from generations. It is an important drug for relieving spasm and epilepsy in children, and is suitable for patients with spleen wind diarrhea.
2. Herbal Medicine of Tang Dynasty: The main symptoms are heartburn, stranguria, dystocia and convulsion.
3. "Japanese Herbs": Sincere.
4. "outline": grinding juice and spreading swollen poison.
5. Yearbook of Traditional Chinese Medicine: Relieving Shock and Pain. Treat epilepsy and joint pain.
6. "Medicinal Materials": soothe the nerves and treat convulsions, convulsions and bloody dysentery for a long time.
3. 18 from China Materia Medica and Dictionary of Traditional Chinese Medicine.
The standard number of Chinese medicine prescription Guazi Yuanbao ng containing snake stone is WS3B09 169 1. Prescription: 500g of snake stone (calcined gastrodia elata) and 50g of chlorite (calcined bezoar). ...
Bo Yan Prime Minister's Army contains Olibanum, Myrrha, Notopterygium Rhizoma, Perillae Radix, Herba Asari, Linderae Radix, Moschus, and Snake contains Stone (calcined), Cinnamomum cassia, Radix Angelicae Dahuricae (without fire), Lignum Dalbergiae Odoriferae, Radix Angelicae Sinensis and Lignum sappan. ...
Baosheng Spindle 2 yuan, Gastrodia elata 5 yuan, Fangfeng 5 yuan, Scorpion 5 yuan, Notopterygium 5 yuan, Snake with Stone (calcined for 7 times, flying in water) 4 Liang. The method is to end the rice paste as a spindle. ...
Snake head pill, borneol 1, musk 1, iron water powder for half a second, herb fog for half a second, snake stone 1 second (vinegar quenching) (add scorpion 1 on one side and aconite root for half a second on the other). ...
Yinyou Sanba: square name: Yinyou three components: cinnabar 1.5, realgar 1.5, snake-bearing stone 1.5, magnet 1.5, Yinyou stone 1.7, and frankincense/kloc-. ...
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Hui Chun Dan Qian, Chen Danxing 2 Liang, Bombyx Batryticatus 3 yuan, Scorpion 3 yuan (washed with wine), Snake-bearing Stone 8 yuan (calcined), Cinnabar 3 yuan, Borneolum Syntheticum 1 Yuan 5 yuan, Musk 1 Yuan 5 yuan. ...
Purple gold ingot money, Chen Danxing 5 money, cicada slough 3 money, licorice 3 money, musk 1 money, snake containing stone 4 Liang (one side plus Bombyx Batryticatus 4 money, Rhizoma Typhonii 4 money, Poria white 4 money, ...
Qianjin powder prescription. Alias: Qianjin powder prescription: frankincense, myrrh, cinnabar, snake stone (vinegar), calomel 15g each. Preparation method: this medicine is fine powder. ...
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The ancient book "Compendium of Materia Medica": [Stone Volume Ten Stones Four] Snake Yellow: Snake Yellow is born in the belly, just like bezoar. Because of its rarity, the world replaces snakes with stones, because they are the same as snakes. There are snakes in Pingnan County, Huanggang, Guangxi. ...
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Puji Fang: [19 1 water disease] Ten waters (attached) are equal. Zijin ointment (published in Sender) treats ten kinds of water vapor. Snake stone (dual-purpose charcoal scale, put the snake stone in a new iron pot and put it in charcoal, ...
Yu Jiwei-yi: [Fifty volumes of therapeutic methods for children] The remedies for damp-heat attack are: black scorpion tail (fried), black ink (burnt), Pinellia ternata (the same as above, one catty made of ginger), snake stone (one coin each), gold and silver foil (ten pieces each), musk (one word) and black snake tail. ...
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