This means that we need to calculate the concentration of [Zn(NH3)6]2+ in 0.6 L of 1.2 M NH3, from which we can infer the concentration of Zn2+. Then, we can use Ksp to determine the amount of dissolved Zn(OH)2.
Because [Zn(NH3)6]2+ is very stable, its concentration is equal to the total Zn2+ concentration, that is:
[Zn(NH3)6]2+ = [Zn2+]
Therefore, [Zn2+] =1.2m.
Now consider [Zn(OH)2]. Let [Zn(OH)2] = x M, then:
zn2+][oh-]^2 =( 1.2 m)(2x)^2 = 4* 10^-3
Through simple algebraic operation, we can get:
X = [OH-] = 0.029
Therefore, [[Zn (OH) 2] = 2x = 0.058mol/L/L.
Therefore, in 0.6 L of 1.2 M NH3, Zn(OH)2 can dissolve at most 0.058 mol.