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In Naruto, which episode did frogs first appear?
Episode 94 See how it works, Anger Spiral Pill?

Taking advantage of his weakness of being afraid of blood, Dou stopped his action, but Naruto finally discovered that Dou was a subordinate of orochimaru. Gang Shou couldn't fight any more, so Jiraiya decided to fight against orochimaru himself.

However, influenced by Gang Shou medicine, Jiraiya's psychic skills can only summon frog Ji, and Naruto's psychic skills are also half-baked, so the strength gap between the two sides is too great. To stop orochimaru, Dou began to attack without scruple. The situation in orochimaru seems to be one-sided, but the battle has just begun. ......

Extended data

The grandson of the gods, the second son of toad, the younger brother of frog Ji, and the frog dragon who lives in the shelter of Miaomu Mountain. The frog dragon is greedy, loves to eat snacks, looks cute, and has an extremely powerful magic wheel in his body.

In the animation, when Naruto finds that he can't cooperate with Toad, Naruto decides to summon Kiki Frog and Dragon Frog, because they have cooperated well before. Naruto was surprised that they all grew up because they were older than him. Frogs claim that this is because they eat a lot of snacks.

However, Naruto later learned that neither frog Ji nor frog dragon were as proficient in water evasion as toad, but decided to continue to cooperate with them anyway, because Naruto found it preferable to cooperate with them.

Later, Naruto discussed with them and decided to try to learn water dodge. Frog Ji and Frog Long began to train the basics of water dodge taught by Mrs. Toad. After several failed attempts, the frog was finally able to escape with water. Later, when Yamato found that the crystal barrier of red-violet could not be broken by conventional means, Naruto summoned Ji Ran and Rana to break through the crystal barrier of red-violet with the iron cannon of the wind shield toad.